Bis(μ-3-carboxy-2-hydroxypropane-1,2-dicarboxylato)bis(diaquazinc)–1,2-bis(pyridin-4-yl)ethene–water (1/1/2)
نویسندگان
چکیده
The asymmetric unit of the title compound, [Zn(2)(C(6)H(6)O(7))(2)(H(2)O)(4)]·C(12)H(10)N(2)·2H(2)O, comprises half of a centrosymmetric complex dimer, half of a 1,2-bis-(pyridin-4-yl)ethene mol-ecule, which lies across an inversion centre, and one lattice water mol-ecule. Carboxyl-ate groups of two dianionic citrate ligands bridge two Zn(II) ions to give the cyclic dimer, with each Zn(II) ion coordinated by four O atoms from the chelating citrate ligand (one hy-droxy and three carboxyl-ate, with one bridging) and two water O atoms, forming a distorted octa-hedral environment [Zn-O = 2.040 (3)-2.244 (3) Å]. In the crystal, O-H⋯O and O-H⋯N hydrogen bonds involving hy-droxy groups and both coordinating and lattice water mol-ecules link the dimers to give a three-dimensional framework structure.
منابع مشابه
Poly[aqua[μ-1,2-bis(pyridin-4-yl)ethene-κ2 N:N′][μ-5-(diphenylphosphinoyl)isophthalato-κ3 O 1,O 1′:O 3]nickel(II)]
In the title compound, [Ni(C(20)H(13)O(5)P)(C(12)H(10)N(2))(H(2)O)](n), the Ni(II) cation is coordinated by three O atoms from two 5-(diphenyl-phosphino-yl)isophthalate anions, two N atoms from two 1,2-bis-(pyridin-4-yl)ethene ligands and one water mol-ecule in a distorted octa-hedral geometry. Both 1,2-bis-(pyridin-4-yl)ethene and 5-(diphenyl-phosphino-yl)iso-phthal-ate bridge the Ni(II) catio...
متن کامل[μ-1,2-Bis(4-pyridyl)ethene-κ2 N:N′]bis[aqua(pyridine-2,6-dicarboxylato-κ3 O 2,N,O 6)copper(II)] dihydrate
In the title dinuclear Cu(II) complex, [Cu(2)(C(7)H(3)NO(4))(2)(C(12)H(10)N(2))(H(2)O)(2)]·2H(2)O, the water-coordinated Cu(II) cation is O,N,O'-chelated by a pyridine-2,6-dicarboxyl-ate (pdc) dianion, and one pyridine N atom from a 1,2-bis-(4-pyrid-yl)ethene ligand coordinates to the Cu(II) cation, completing the CuN(2)O(3) distorted square-pyriamidial geometry. The Cu-O(water) bond [2.388 (4)...
متن کاملCrystal structure of catena-poly[[[tetraaquairon(II)]-trans-μ-1,2-bis(pyridin-4-yl)ethene-κ2 N:N′] bis(p-toluenesulfonate) methanol disolvate]
In the title polymeric complex, {[Fe(C12H10N2)2(H2O)4](CH3C6H4SO3)2·2CH3OH} n , the FeII cation, located on an inversion centre, is coordinated by four water mol-ecules in the equatorial positions and two 1,2-bis-(pyridin-4-yl)ethene mol-ecules in the axial positions. This results in a distorted octa-hedral geometry for the [N2O4] coordination polyhedron. The 1,2-bis-(pyridin-4-yl)ethene mol-ec...
متن کاملBis(μ-2-carboxymethyl-2-hydroxybutanedioato)bis[diaquamanganese(II)]–1,2-bis(pyridin-4-yl)ethene–water (1/1/2)
The asymmetric unit of the title compound, [Mn2(C6H6O7)2(H2O)4]·C12H10N2·2H2O, contains half of the centrosymmetric Mn complex dimer, half of a 1,2-bis-(pyridin-4-yl)ethene mol-ecule, which lies across an inversion center, and one water mol-ecule. Two citrate ligands bridge two Mn(II) ions, and each Mn(II) atom is coordinated by four O atoms from the citrate ligands (one from hy-droxy and three...
متن کاملcatena-Poly[[[diaquabis[1,2-bis(pyridin-4-yl)diazene]copper(II)]-μ-1,2-bis(pyridin-4-yl)diazene] bis(perchlorate)]
In the title compound, {[Cu(C10H8N4)3(H2O)2](ClO4)2} n , the coordination environment of the cationic Cu(II) atom is distorted octa-hedral, formed by pairs of symmetry-equivalent 1,2-bis-(pyridin-4-yl)diazene ligands, bridging 1,2-bis-(pyridin-4-yl)diazene ligands and two non-equivalent water mol-ecules. The 1,2-bis-(pyridin-4-yl)diazene mol-ecules form polymeric chains parallel to [-101] via a...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 68 شماره
صفحات -
تاریخ انتشار 2012